Reaction/Diffusion at Electrode/Solution Interfaces: The EC2 Reaction
نویسنده
چکیده
A closed form analytical expression is derived for the normalized current versus potential response expected for a rotating disc electrode in which an initial fast electron transfer reaction is followed by a homogeneous electrochemical reaction which exhibits second order kinetics. The effect of the homogeneous reaction on the shape of the voltammetric response curve is calculated.
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